This is because people breathe oxygen gas as O2 which is in a different form from the oxygen molecules (tiny tiny parts!) found in H2O (water), and easier for us to absorb than the dissolved O2 gas bubbles (which fish can "breathe" through their gills). If you'd like to look into the science more closely this is a handy link ...
http://science.howstuffworks.com/question386.htm
Of course we can get around this by using a whole lot of artificial (made by us!) technologies. Do you recognise these ones?
Or could we just swallow gilly weed like Harry Potter and grow gills and webbed hands and feet ... ? What do you think :)?
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